File Nos. 2-32773
811-01835
As Filed with the Securities and Exchange Commission on February 7, 2013

SECURITIES AND EXCHANGE COMMISSION
Washington, D.C. 20549 

              FORM N-1A
       REGISTRATION STATEMENT
                UNDER
    THE SECURITIES ACT OF 1933     [X]
   Pre-Effective Amendment No.     [_]
  Post-Effective Amendment No. 76  [X]
               and/or
       REGISTRATION STATEMENT
                UNDER
THE INVESTMENT COMPANY ACT OF 1940  [X]
         Amendment No. 59           [X]
  (Check appropriate box or boxes)

          -----------------

         PIONEER VALUE FUND

(Exact Name of Registrant as Specified in Charter)

60 State Street, Boston, Massachusetts 02109
(Address of Principal Executive Offices) (Zip Code)

Registrant's Telephone Number, including Area Code: (617) 742-7825

Terrence J. Cullen, Pioneer Investment Management, Inc.
60 State Street, Boston, Massachusetts 02109
(Name and Address of Agent for Service)

It is proposed that this filing will become effective (check appropriate box):

[X]immediately upon filing pursuant to paragraph (b)
[_]on [date] pursuant to paragraph (b)
[_]60 days after filing pursuant to paragraph (a)(1)
[_]on [date] pursuant to paragraph (a)(1)
[_]75 days after filing pursuant to paragraph (a)(2)
[_]on [date] pursuant to paragraph (a)(2) of Rule 485.

If appropriate, check the following box:

[_]This post-effective amendment designates a new effective date for a
previously filed post-effective amendment.

SIGNATURES

Pursuant to the requirements of the Securities Act of 1933, as amended, and the Investment Company Act of 1940, as amended, the Fund certifies that it meets all of the requirements for effectiveness of this registration statement under Rule 485(b) under the Securities Act of 1933 and has has duly caused this Post-Effective Amendment No. 76 to its registration statement to be signed on its behalf by the undersigned, duly authorized, in the City of Boston, and the Commonwealth of Massachusetts, on the 7th day of February, 2013.

PIONEER VALUE FUND 

By:  /s/ Daniel K. Kingsbury
     -----------------------------
     Daniel K. Kingsbury
     Executive Vice President

Pursuant to the requirements of the Securities Act of 1933, this registration statement has been signed below by the following persons in the capacities indicated below on February 7, 2013: 

Signature                                 Title

John F. Cogan, Jr.*                       President, Principal Executive
John F. Cogan, Jr.                        Officer) and Trustee

Mark E. Bradley*                          Treasurer (Principal Financial and
Mark E. Bradley                           Accounting Officer)

David R. Bock*                            Trustee
David R. Bock

Benjamin M. Friedman*                     Trustee
Benjamin M. Friedman

Margaret B. W. Graham*                    Trustee
Margaret B. W. Graham

/s/ Daniel K. Kingsbury                   Executive Vice President and
    Daniel K. Kingsbury                   Trustee

Thomas J. Perna*                          Chairman of the Board and Trustee
Thomas J. Perna

Marguerite A. Piret*                      Trustee
Marguerite A. Piret

Stephen K. West*                          Trustee
Stephen K. West

*By:  /s/ Daniel K. Kingsbury             Dated: February 7, 2013
      ----------------------------------
      Daniel K. Kingsbury
      Attorney-in-Fact

                                EXHIBIT INDEX

Exhibit No. Description 

EX-101.INS  XBRL Instance Document

EX-101.SCH  XBRL Taxonomy Extension Schema Document

EX-101.CAL  XBRL Taxonomy Extension Calculation Linkbase

EX-101.DEF  XBRL Taxonomy Extension Definition Linkbase

EX-101.LAB  XBRL Taxonomy Extension Labels Linkbase

EX-101.PRE  XBRL Taxonomy Extension Presentation Linkbase

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